Document Details

Document Type : Article In Journal 
Document Title :
COMPLEXES OF MOLYBDENUM (II) AND TUNGSTEN (II) WITH 2-PENTYNE CONTAINING PHOSPHITE LIGANDS
مجمعات الموليبدينوم (الثاني) والتنغستين (الثاني) مع 2 - PENTYNE يغاندس فسفيت المحتوية
 
Subject : COMPLEXES OF MOLYBDENUM (II) AND TUNGSTEN (II) WITH 2-PENTYNE CONTAINING PHOSPHITE LIGANDS 
Document Language : English 
Abstract : When reaction between equimolar quantities of [MoI2(CO)(NCMe) (h2-EtC2Me)2] and one equavalat of phosphites groups P(OR)3 the yield will take different way, where M = Mo the 2-pentyne displaced products, [Mol2(CO)(NCMe){P(OR)3}(h2-EtC2Me)] (R=Ph, iPr) (1) and (2) and with M = W afforded the acetonitrile displaced products [Wl2(CO){P(OR)3} (h2-EtC2Me)2] (R = Me, Et, 1Pr, Ph) (3-6). Reaction of [Ml2(CO)(NCMe)(h2-EtC2Me)2] with two equivalents of P(OR)3 gave the mono (2-Pentyne) complexes, [Ml2(CO){P(OR)3}2 (h2-EtC2Me)] (M = Mo or w; R = Me, Et, iPr, nBu, Ph)6-15. 
ISSN : 1012-1319 
Journal Name : Science Journal 
Volume : 20 
Issue Number : 3 
Publishing Year : 1424 AH
2004 AD 
Article Type : Article 
Added Date : Sunday, February 20, 2011 

Researchers

Researcher Name (Arabic)Researcher Name (English)Researcher TypeDr GradeEmail
مطلق الجحدليAl-jahdali, Mutlaq ResearcherDoctorate 

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